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Direct Catalytic Synthesis of N ‐Arylcarbamates from CO 2 , Anilines and Alcohols
Author(s) -
Tamura Masazumi,
Miura Ayaka,
Honda Masayoshi,
Gu Yu,
Nakagawa Yoshinao,
Tomishige Keiichi
Publication year - 2018
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201801443
Subject(s) - catalysis , reactivity (psychology) , methanol , chemistry , organic chemistry , combinatorial chemistry , medicine , alternative medicine , pathology
The direct catalytic synthesis of carbamates from CO 2 , amines and methanol was achieved by controlling both the reaction equilibrium and the reactivity of the three components. The combination of CeO 2 and 2‐cyanopyridine was an effective catalyst, providing various carbamates including N ‐arylcarbamates in high selectivities.