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Sustainable Manganese‐Catalyzed C−H Activation/Hydroarylation of Imines
Author(s) -
Liang YuFeng,
Massignan Leonardo,
Ackermann Lutz
Publication year - 2018
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201800144
Subject(s) - aldimine , catalysis , manganese , chemistry , substrate (aquarium) , combinatorial chemistry , selectivity , environmentally friendly , scope (computer science) , organic chemistry , computer science , oceanography , geology , ecology , biology , programming language
Expedient C−H additions of heteroarenes onto aldimines were realized by a sustainable manganese catalysis manifold within a removable directing group strategy. The C−H activation features most user‐friendly reaction conditions, excellent chemo‐ and position‐selectivity as well as ample substrate scope. Detailed experimental mechanistic studies suggest an organometallic C−H manganesation mode of action.