Sustainable Manganese‐Catalyzed C−H Activation/Hydroarylation of Imines | Zendy

Liang YuFeng | Zendy; Massignan Leonardo | Zendy; Ackermann Lutz | Zendy

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Sustainable Manganese‐Catalyzed C−H Activation/Hydroarylation of Imines

Author(s) -

Liang YuFeng,

Massignan Leonardo,

Ackermann Lutz

Publication year - 2018

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201800144

Subject(s) - aldimine , catalysis , manganese , chemistry , substrate (aquarium) , combinatorial chemistry , selectivity , environmentally friendly , scope (computer science) , organic chemistry , computer science , oceanography , geology , ecology , biology , programming language

Expedient C−H additions of heteroarenes onto aldimines were realized by a sustainable manganese catalysis manifold within a removable directing group strategy. The C−H activation features most user‐friendly reaction conditions, excellent chemo‐ and position‐selectivity as well as ample substrate scope. Detailed experimental mechanistic studies suggest an organometallic C−H manganesation mode of action.

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