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Palladium Nanoparticles Stabilized by Metal–Carbon Covalent Bonds as an Expeditious Catalyst for the Oxidative Dehydrogenation of Nitrogen Heterocycles
Author(s) -
Sun XiaoTao,
Zhu Jie,
Xia YunTao,
Wu Lei
Publication year - 2017
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201700370
Subject(s) - dehydrogenation , covalent bond , palladium , catalysis , chemistry , solvent , metal , nanoparticle , nitrogen , carbon fibers , organic chemistry , photochemistry , polymer chemistry , materials science , nanotechnology , composite number , composite material
The first method for the dehydrogenation of nitrogen heterocycles catalyzed by a palladium nanocatalyst was developed. Carbon–metal covalent‐bond‐stabilized nanoparticles were found to be efficient for the dehydrogenation process in the presence of tert ‐butyl hydroperoxide. A variety of N‐heterocycles were transformed into functionalized quinolines in medium to excellent yields in water as the solvent under mild conditions by a simple operation.