Palladium Nanoparticles Stabilized by Metal–Carbon Covalent Bonds as an Expeditious Catalyst for the Oxidative Dehydrogenation of Nitrogen Heterocycles | Zendy

Sun XiaoTao | Zendy; Zhu Jie | Zendy; Xia YunTao | Zendy; Wu Lei | Zendy

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Palladium Nanoparticles Stabilized by Metal–Carbon Covalent Bonds as an Expeditious Catalyst for the Oxidative Dehydrogenation of Nitrogen Heterocycles

Author(s) -

Sun XiaoTao,

Zhu Jie,

Xia YunTao,

Wu Lei

Publication year - 2017

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201700370

Subject(s) - dehydrogenation , covalent bond , palladium , catalysis , chemistry , solvent , metal , nanoparticle , nitrogen , carbon fibers , organic chemistry , photochemistry , polymer chemistry , materials science , nanotechnology , composite number , composite material

The first method for the dehydrogenation of nitrogen heterocycles catalyzed by a palladium nanocatalyst was developed. Carbon–metal covalent‐bond‐stabilized nanoparticles were found to be efficient for the dehydrogenation process in the presence of tert ‐butyl hydroperoxide. A variety of N‐heterocycles were transformed into functionalized quinolines in medium to excellent yields in water as the solvent under mild conditions by a simple operation.

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