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Core–Shell‐Structured NiS 2 @Ni‐B i Nanoarray for Efficient Water Oxidation at Near‐Neutral pH
Author(s) -
Ma Xiao,
Ma Min,
Liu Danni,
Hao Shuai,
Qu Fengli,
Du Gu,
Asiri Abdullah M.,
Sun Xuping
Publication year - 2017
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201700350
Subject(s) - overpotential , electrochemistry , catalysis , oxygen evolution , electrolyte , chemical engineering , materials science , water splitting , inorganic chemistry , electrode , chemistry , organic chemistry , engineering , photocatalysis
The development of high‐performance and cost‐effective water oxidation catalysts operating under mild conditions is attractive for the conversion of electricity into chemical fuels. In this communication, we report the in situ electrochemical development of a Ni‐B i layer (5–8 nm thick) on a NiS 2 nanoarray supported on carbon cloth (i.e., NiS 2 @Ni‐B i /CC) for efficient water oxidation in 0.1 m potassium borate electrolyte at pH 9.2. As a durable 3 D catalyst electrode, core–shell‐structured NiS 2 @Ni‐B i /CC shows excellent catalytic activity for water oxidation and approaches a geometrical catalytic current density of 20 mA cm −2 at an overpotential of 486 mV, with long‐term electrochemical stability for at least 24 h with a high turnover frequency of 0.28 mol O 2 s −1 at an overpotential of 500 mV and nearly 100 % Faradic efficiency for oxygen evolution.