Single‐Pot Conversion of Tetrahydrofurfuryl Alcohol into Tetrahydropyran over a Ni/HZSM‐5 Catalyst under Aqueous‐Phase Conditions | Zendy

Soghrati Elmira | Zendy; Choong Catherine | Zendy; Poh Chee Kok | Zendy; Kawi Sibudjing | Zendy; Borgna Armando | Zendy

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Single‐Pot Conversion of Tetrahydrofurfuryl Alcohol into Tetrahydropyran over a Ni/HZSM‐5 Catalyst under Aqueous‐Phase Conditions

Author(s) -

Soghrati Elmira,

Choong Catherine,

Poh Chee Kok,

Kawi Sibudjing,

Borgna Armando

Publication year - 2017

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201601708

Subject(s) - hydrogenolysis , bifunctional , catalysis , tetrahydropyran , alcohol , aqueous solution , chemistry , yield (engineering) , organic chemistry , bond cleavage , phase (matter) , materials science , ring (chemistry) , metallurgy

Ni‐based catalysts were examined in the hydrogenolysis of tetrahydrofurfuryl alcohol, resulting in the selective C−O bond cleavage to produce 1,5‐pentanediol, along with 1,2,5‐pentanetriol, which was detected for the first time under aqueous‐phase conditions. 70 % yield to tetrahydropyran was achieved using one‐pot conversion over bifunctional Ni/HZSM‐5 catalysts.

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