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Recent Advances in Cascade Reactions Initiated by Alcohol Oxidation
Author(s) -
Faisca Phillips Ana Maria,
Pombeiro Armando J. L.,
Kopylovich Maximilian N.
Publication year - 2017
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201601176
Subject(s) - atom economy , cascade , alcohol , alcohol oxidation , combinatorial chemistry , redox , chemistry , construct (python library) , biochemical engineering , stereoselectivity , molecule , organic chemistry , nanotechnology , computer science , catalysis , materials science , engineering , chromatography , programming language
In this review, we attempt to answer the question: how can we construct complex functionalized molecules with significant added value from cheap and readily available alcohols in the simplest and most efficient manner? Accordingly, recent developments (mainly from the last five years) in the field of one‐pot multiple transformations of alcohols are overviewed in terms of process simplification and optimization; sustainability; and atom, bond, step, and redox economy. Particular attention is paid to chemo‐ and stereoselective transformations with specific formation of particular bonds and configurations, leaving other parts of substrates unchanged.
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