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Ligand‐Promoted Palladium‐Catalyzed C−H Acetoxylation of Simple Arenes
Author(s) -
Valderas Carolina,
Naksomboon Kananat,
FernándezIbáñez M. Ángeles
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600757
Subject(s) - palladium , catalysis , chemistry , ligand (biochemistry) , reactivity (psychology) , selectivity , combinatorial chemistry , phenols , organic chemistry , receptor , medicine , biochemistry , alternative medicine , pathology
The palladium‐catalyzed C−H oxidation of simple arenes is an attractive strategy to obtain phenols, which have many applications in the fine chemicals industry. Although some advances have been made in this research area, low reactivity and selectivity are, in general, observed. This report describes a new catalytic system for the efficient C−H acetoxylation of simple arenes based on Pd(OAc) 2 and a pyridinecarboxylic acid ligand.