Visible‐Light Photocatalytic Aerobic Benzylic C(sp 3 )−H Oxygenations with the  3 DDQ*/ tert ‐Butyl Nitrite Co‐catalytic System | Zendy

Rusch Fabian | Zendy; Schober JanChristian | Zendy; Brasholz Malte | Zendy

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Visible‐Light Photocatalytic Aerobic Benzylic C(sp 3 )−H Oxygenations with the 3 DDQ*/ tert ‐Butyl Nitrite Co‐catalytic System

Author(s) -

Rusch Fabian,

Schober JanChristian,

Brasholz Malte

Publication year - 2016

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201600704

Subject(s) - catalysis , nitrite , chemistry , photocatalysis , benzoquinone , photochemistry , medicinal chemistry , organic chemistry , nitrate

Photocatalytic aerobic benzylic C(sp 3 )−H oxygenations of aromatic hydrocarbons and C3‐substituted indoles were studied by employing a co‐catalytic system of 3 DDQ* (DDQ=2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone) and tert ‐butyl nitrite. The superior efficiency of these reaction conditions was demonstrated by comparison with the analogous thermal protocol, and a range of substrates could be oxidized catalytically and selectively in good yields.

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