Premium
Structural Analysis and Electrochemical Properties of Bimetallic Palladium–Platinum Aerogels Prepared by a Two‐Step Gelation Process
Author(s) -
Oezaslan Mehtap,
Herrmann AnneKristin,
Werheid Matthias,
Frenkel Anatoly I.,
Nachtegaal Maarten,
Dosche Carsten,
Laugier Bonnaud Céline,
Yilmaz Hale Ceren,
Kühn Laura,
Rhiel Erhard,
Gaponik Nikolai,
Eychmüller Alexander,
Schmidt Thomas Justus
Publication year - 2017
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600667
Subject(s) - bimetallic strip , materials science , palladium , dissolution , electrochemistry , chemical engineering , platinum , cyclic voltammetry , noble metal , nanoparticle , aerogel , catalysis , metal , transition metal , nanotechnology , electrode , chemistry , metallurgy , organic chemistry , engineering
Multimetallic aerogels have emerged as promising unsupported and high‐surface‐area metal materials for different applications in heterogeneous catalysis and electrochemistry, which are fabricated using a gelation process characterized by the controlled aggregation of metallic nanoparticles to form a macroscopic network structure in aqueous solution. However, the achievement of the structural homogeneity of the multimetallic aerogels in terms of the diameter of the nanochains and the chemical composition at the nano‐ and the macro‐scale is still a great challenge. In this paper, we investigated two Pd‐Pt aerogels prepared by the two‐step gelation method. The structural homogeneity and chemical distribution of both metals inside the aerogels were analyzed by using high‐resolution (scanning) transmission microscopy, energy‐dispersive X‐ray spectroscopy, extended X‐ray absorption fine structure spectroscopy and cyclic voltammetry. The Pd‐Pt aerogels show the presence of Pd/Pt‐rich domains inside the long‐range framework. It is evident that the initial monometallic features dominate over alloying during the gelation process. Although the same synthetic approach for Pd‐Pt aerogels with different atomic ratios was used, we observed that the sizes of these monometallic domains varied strongly between the Pd‐rich and Pt‐rich aerogels. The presence of such metal clusters influenced the electrochemical robustness of the Pd‐Pt aerogels dramatically. Electrochemical durability investigations revealed that the aerogels with a high content of Pd are less stable because of the gradual dissolution of the less noble metal particularly inside the Pd‐rich domains. A chemical and structural homogeneity might improve the lifetime of the Pd‐Pt aerogels under electrochemical conditions. In this work, we provide a better understanding of the structure and chemical distribution of the bimetallic aerogel framework prepared by the two‐step gelation process.