Premium
Catalyst‐Triggered Highly Selective C−S and C−Se Bond Formation by C−H Activation
Author(s) -
Yang Yong,
Li Wanmei,
Ying Beibei,
Liao Hanxiao,
Shen Chao,
Zhang Pengfei
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600589
Subject(s) - thioether , diselenide , chemistry , catalysis , selenide , indole test , diphenyl diselenide , iodine , nickel , metal , medicinal chemistry , selenium , stereochemistry , combinatorial chemistry , organic chemistry
Nickel or iron salts catalyzing the selective synthesis of 3,3‐indolyl disulfide (diselenide) and 3,3‐indolyl thioether (selenide) directly from indole through C−H activation are reported. The effect of iodine element was beneficial in the novel metal‐catalyzed circulation system. A wide variety of functional groups could be tolerated under the reaction conditions.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom