Premium
Conjugated Dienyl Derivatives by Green Bisallylic Substitution: Synthetic and Mechanistic Insight
Author(s) -
Cazorla Clément,
Billamboz Muriel,
ChevrinVillette Carole,
Hapiot Frédéric,
Monflier Eric,
Len Christophe
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600343
Subject(s) - conjugated system , catalysis , substitution (logic) , palladium , chemistry , combinatorial chemistry , catalytic cycle , microwave irradiation , reaction mechanism , organic chemistry , computer science , polymer , programming language
The first palladium‐catalyzed bisallylic substitution on biobased bisallylic derivatives was explored. The developed method, performed under green conditions with microwave irradiation, led to valuable conjugated dienes. The mechanism was studied by ESI‐MS and NMR spectroscopy, which highlighted the involvement of bis‐π‐allylpalladium complexes in the catalytic cycle.