Premium
Three‐Dimensional Metal–Organic Framework Graphene Nanocomposite as a Highly Efficient and Stable Electrocatalyst for the Oxygen Reduction Reaction in Acidic Media
Author(s) -
Sohrabi Samaneh,
Dehghanpour Saeed,
Ghalkhani Masoumeh
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600298
Subject(s) - electrocatalyst , graphene , porphyrin , metal organic framework , nanocomposite , materials science , catalysis , pyrolysis , inorganic chemistry , chemistry , chemical engineering , electrode , electrochemistry , nanotechnology , photochemistry , organic chemistry , adsorption , engineering
We report on the design of a bio‐inspired composite as a noble‐metal‐free electrocatalyst for the oxygen reduction reaction (ORR). The composite is made from the assembly of pyridine‐functionalized graphene (G‐py) and a 3 D metal–organic framework (MOF) deposited onto a glassy carbon electrode (GCE). The 3 D heme‐like MOF was synthesized from tetrakis(4‐carboxyphenyl)porphyrin iron(III) chloride and Zr 6 clusters for the assembly of the stable porous coordination network. G‐py, which possesses an axial ligand to anchor to the centers of porphyrin in the MOF, results in a significant change in the electronic and geometric structure of centers, which enhances the rate of ORR and durability during cycling in acidic media. The occurrence potential of the ORR by the composite is shifted to the positive potential near 100 mV. Our results introduce a new strategy for the rational design of inexpensive and highly stable oxygen reduction electrocatalysts for fuel cells without the requirement of pyrolysis.