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Palladium‐Catalyzed Carbonylative Synthesis of Aryl Formates under Mild Conditions
Author(s) -
Jiang LiBing,
Li Rui,
Li HaoPeng,
Qi Xinxin,
Wu XiaoFeng
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600165
Subject(s) - carbonylation , palladium , catalysis , aryl , formic acid , chemistry , organic chemistry , combinatorial chemistry , carbon monoxide , alkyl
Abstract Aryl formates have been extensively applied as CO sources in CO‐free carbonylation reactions. However, there are no catalytic synthetic procedures for their preparation. In this manuscript, we developed a convenient palladium‐catalyzed procedure for the synthesis of aryl formates. Good yields were achieved under mild reaction conditions with formic acid as the formyl source.