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Pillared Sn‐MWW Prepared by a Solid‐State‐Exchange Method and its Use as a Lewis Acid Catalyst
Author(s) -
Ren Limin,
Guo Qiang,
Orazov Marat,
Xu Dandan,
Politi Dorothea,
Kumar Prashant,
Alhassan Saeed M.,
Mkhoyan K. Andre,
Sidiras Dimitrios,
Davis Mark E.,
Tsapatsis Michael
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600120
Subject(s) - lewis acids and bases , catalysis , chemistry , leaching (pedology) , boron , tin , tetrachloride , solid state , ion exchange , inorganic chemistry , lewis acid catalysis , heterogeneous catalysis , disaccharide , polymer chemistry , organic chemistry , ion , environmental science , soil science , soil water
Pillared Sn‐MWW (Sn‐MWW(SP)‐SSE) was prepared through a solid‐state‐exchange (SSE) route. The pillared structure was inherited from pillared B‐MWW, and Sn was inserted in the framework by boron leaching and solid‐state‐exchange with tin tetrachloride pentahydrate. The Sn‐MWW(SP)‐SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer–Villiger oxidation, and mono‐ and disaccharide isomerizations.