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Hierarchical NaY Zeolites for Lactic Acid Dehydration to Acrylic Acid
Author(s) -
Lari Giacomo M.,
Puértolas Begoña,
Frei Matthias S.,
Mondelli Cecilia,
PérezRamírez Javier
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201600102
Subject(s) - calcination , catalysis , selectivity , chemistry , acrylic acid , mesoporous material , lactic acid , inorganic chemistry , molecular sieve , zeolite , heterogeneous catalysis , lewis acids and bases , chemical engineering , organic chemistry , polymer , copolymer , biology , bacteria , engineering , genetics
The industrial viability of heterogeneous catalysts for the gas‐phase conversion of lactic acid to acrylic acid will strongly depend on their selectivity and durability. Here, we initially screened various aluminum‐rich zeolites confirming that NaY is the most efficient catalyst for this reaction. This material was modified by sequential dealumination and alkaline treatment attaining a solid featuring a hierarchical distribution of micro‐ and mesopores, reduced Lewis acidity, and increased basicity owing to the presence of well‐dispersed sodium ions interacting with external siloxy groups, as evidenced by in‐depth characterization. These properties were crucial for determining higher selectivity (75 %) and minimizing the activity loss in a 6 h run. Remarkably, the catalyst gained in selectivity and stability upon reuse in consecutive cycles. This was ascribed to the depletion of the stronger basic sites and the clustering of sodium into oxidic particles upon the intermediate calcination.