Visible‐Light‐Mediated Aromatic Substitution Reactions of Cyanoarenes with 4‐Alkyl‐1,4‐dihydropyridines through Double Carbon–Carbon Bond Cleavage | Zendy

Nakajima Kazunari | Zendy; Nojima Sunao | Zendy; Sakata Ken | Zendy; Nishibayashi Yoshiaki | Zendy

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Visible‐Light‐Mediated Aromatic Substitution Reactions of Cyanoarenes with 4‐Alkyl‐1,4‐dihydropyridines through Double Carbon–Carbon Bond Cleavage

Author(s) -

Nakajima Kazunari,

Nojima Sunao,

Sakata Ken,

Nishibayashi Yoshiaki

Publication year - 2016

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201600037

Subject(s) - chemistry , alkyl , reagent , bond cleavage , catalysis , electrophilic aromatic substitution , cleavage (geology) , carbon–carbon bond , photochemistry , substitution reaction , carbon fibers , double bond , medicinal chemistry , organic chemistry , materials science , fracture (geology) , composite number , composite material

Novel aromatic substitution reactions of cyanoarenes with 4‐alkyl‐1,4‐dihydropyridines as alkylating reagents in the presence of a catalytic amount of a photoredox catalyst proceed smoothly to give the corresponding alkyl‐substituted arenes in good to high yields. The present reaction system realizes a novel C−C bond‐forming reaction between two fragments generated from the C−C bond‐cleavage reactions of two independent substrates.

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