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Carbon Dioxide/Epoxide Reactions Catalyzed by Bimetallic Salalen Aluminum Complexes
Author(s) -
Cozzolino Mariachiara,
Press Konstantin,
Mazzeo Mina,
Lamberti Marina
Publication year - 2016
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201500856
Subject(s) - cyclohexene oxide , epoxide , catalysis , bimetallic strip , propylene oxide , ammonium bromide , propylene carbonate , cyclohexene , chemistry , inorganic chemistry , selectivity , carbonate , oxide , bromide , organic chemistry , ethylene oxide , electrode , copolymer , electrochemistry , pulmonary surfactant , biochemistry , polymer
Four new bimetallic aluminum complexes that bear salalen ligands were synthesized and characterized. They were employed as catalysts in the reaction of CO 2 with both cyclohexene oxide and propylene oxide with tetrabutyl ammonium bromide as the cocatalyst. The effect of the reaction conditions on the productivity and selectivity of the catalytic system was evaluated. Under the optimized reaction conditions, cis ‐cyclohexene carbonate and propylene carbonate were obtained as exclusive products, respectively. Interestingly, in the production of cis ‐cyclohexene carbonate, turnover frequencies comparable to those of the most active systems described in the literature were obtained. Moreover the catalytic system was active even if it was operated at a low CO 2 pressure (0.2 MPa) and with a low catalyst loading (0.04 mol %).