Polystyrene‐Supported Triphenylsilyl Chloride for the Silylation‐Based Kinetic Resolution of Secondary Alcohols | Zendy

Akhani Ravish K. | Zendy; Clark Robert W. | Zendy; Yuan Liang | Zendy; Wang Li | Zendy; Tang Chuanbing | Zendy; Wiskur Sheryl L. | Zendy

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Polystyrene‐Supported Triphenylsilyl Chloride for the Silylation‐Based Kinetic Resolution of Secondary Alcohols

Author(s) -

Akhani Ravish K.,

Clark Robert W.,

Yuan Liang,

Wang Li,

Tang Chuanbing,

Wiskur Sheryl L.

Publication year - 2015

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201500173

Subject(s) - kinetic resolution , silylation , selectivity , chemistry , polystyrene , enantiomer , styrene , organic chemistry , chloride , polymer , resolution (logic) , alcohol , polymer chemistry , catalysis , copolymer , enantioselective synthesis , artificial intelligence , computer science

A silyl chloride derivatized styrene polymer was employed in the silylation‐based kinetic resolution of secondary alcohols for chromatography‐free separation of alcohol enantiomers. Synthetically useful selectivity factors were obtained; furthermore, the polymer was recycled for use in a subsequent kinetic resolution, and it maintained its selectivity and integrity.

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