Cp*Co III ‐Catalyzed CH Activation of (Hetero)arenes: Expanding the Scope of Base‐Metal‐Catalyzed CH Functionalizations | Zendy

Yoshikai Naohiko | Zendy

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Cp*Co III ‐Catalyzed CH Activation of (Hetero)arenes: Expanding the Scope of Base‐Metal‐Catalyzed CH Functionalizations

Author(s) -

Yoshikai Naohiko

Publication year - 2015

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201403017

Subject(s) - catalysis , chemistry , electrophile , cationic polymerization , reactivity (psychology) , medicinal chemistry , metal , surface modification , base (topology) , rhodium , stereochemistry , combinatorial chemistry , polymer chemistry , organic chemistry , medicine , mathematical analysis , alternative medicine , mathematics , pathology

Directed activation: Cationic Cp*Co III (Cp*=1,2,3,4,5‐pentamethylcyclopentadienyl) complexes, either well‐defined or in situ‐generated, promote catalytic functionalization of arene CH bonds with a variety of electrophilic reaction partners by directed CH activation. These complexes not only emulate known reaction patterns of Cp*Rh III analogues, but also exhibit remarkable catalytic activity or unique reactivity. DG=Directing group.

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