Premium
Cross‐Coupling Knows No Limits: Assessing the Synthetic Potential of the Palladium‐Catalysed Cross‐Coupling of Organolithiums
Author(s) -
Firth James D.,
O'Brien Peter
Publication year - 2015
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201402886
Subject(s) - palladium , coupling (piping) , coupling reaction , chemistry , computational chemistry , combinatorial chemistry , chemical physics , polymer chemistry , materials science , organic chemistry , catalysis , composite material
Organolithiums have passed the test! Previously considered too reactive and unstable, organolithiums have been tamed and can now participate successfully in palladium‐catalysed cross‐coupling with aryl/vinyl bromides and triflates.