Recycling Powered by Release of Carbon Dioxide | Zendy

Laurell Nash Anna | Zendy; Widyan Khalid | Zendy; Moberg Christina | Zendy

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Recycling Powered by Release of Carbon Dioxide

Author(s) -

Laurell Nash Anna,

Widyan Khalid,

Moberg Christina

Publication year - 2014

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201402765

Subject(s) - exergonic reaction , reagent , enantiomer , carbon dioxide , chemistry , catalysis , chemical engineering , enantiomeric excess , organic chemistry , combinatorial chemistry , nanotechnology , materials science , enantioselective synthesis , engineering

In a cyclic process, fed with external chemical energy generated by the transformation of a compound with high chemical potential to carbon dioxide, the undesired enantiomer from a catalytic asymmetric reaction is continuously recycled to starting reagent. This minor enantiomer recycling is characterized by gradually increasing yields and product enantiomeric ratios. The requirements for maintaining a cyclic procedure are discussed; the necessity of a coupled exergonic process is demonstrated experimentally.

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