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Ligands Control Reactivity and Selectivity in Palladium‐Catalyzed Functionalization of Unactivated C sp 3 H Bonds
Author(s) -
FernándezIbáñez M. Ángeles
Publication year - 2014
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201402269
Subject(s) - surface modification , palladium , reactivity (psychology) , chemistry , selectivity , catalysis , ligand (biochemistry) , inert , combinatorial chemistry , organic chemistry , receptor , medicine , biochemistry , alternative medicine , pathology
Ligands at the wheel: The pivotal role of ligands for the palladium‐catalyzed functionalization of remote C sp 3 H bonds has been demonstrated. The presence of the ligand enhances the reactivity of the inert C sp 3 H bond and controls the selectivity of the process. DG=Directing group, FG=functional group.
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