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Cu II and Cu 0 Catalyzed Mono Borylation of Unsaturated Hydrocarbons with B 2 pin 2 : Entering into the Water
Author(s) -
Stavber Gaj,
Časar Zdenko
Publication year - 2014
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201402176
Subject(s) - borylation , catalysis , chemistry , boron , aqueous medium , stereoselectivity , aqueous solution , hydrocarbon , organic chemistry , inorganic chemistry , alkyl , aryl
Purity in water: An interesting course of development took place recently in the area of boron additions to unsaturated precursors. The first Cu II and Cu 0 catalyzed B 2 pin 2 additions to alkenes and alkynes in/on pure aqueous media evolved from discovery on racemic versions to asymmetric variants and pharmaceutical applications. All presented methods provide significantly simplified catalytic systems and perform with high efficiency and stereoselectivity in/on pure water.