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High‐Temperature Polymer Electrolyte Fuel Cell Using Poly(vinylphosphonic acid) as an Electrolyte Shows a Remarkable Durability
Author(s) -
Berber Mohamed R.,
Fujigaya Tsuyohiko,
Nakashima Naotoshi
Publication year - 2014
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300884
Subject(s) - electrolyte , phosphoric acid , electrocatalyst , polymer , chemical engineering , membrane , materials science , dopant , membrane electrode assembly , chemistry , inorganic chemistry , polymer chemistry , electrode , organic chemistry , electrochemistry , doping , biochemistry , optoelectronics , engineering
The development of a high‐performance, durable, and less expensive membrane electrode assembly (MEA) composed of a polymer electrolyte membrane and electrocatalysts is important for developing fuel cells. Herein, we described the design and fabrication of an electrocatalyst with carbon black, polybenzimidazole doped with poly(vinylphosphonic acid) (PVPA), and platinum nanoparticles as an electron‐conducting support material, an electrolyte, and a metal catalyst, respectively. Most importantly, we used PVPA in place of phosphoric acid, which is a widely used acid dopant, as the acid dopant for both the electrocatalyst and the polymer electrolyte membrane. We reported that the use of PVPA is crucial for the high performance of the MEA because it prevented the leaching of acid molecules from the MEA, which led to high durability compared to that of the phosphoric acid‐doped MEAs.