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Stable Performance of Ni Catalysts in the Dry Reforming of Methane at High Temperatures for the Efficient Conversion of CO 2 into Syngas
Author(s) -
Mette Katharina,
Kühl Stefanie,
Düdder Hendrik,
Kähler Kevin,
Tarasov Andrey,
Muhler Martin,
Behrens Malte
Publication year - 2014
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300699
Subject(s) - catalysis , carbon dioxide reforming , syngas , hydrotalcite , chemical engineering , materials science , methane , precipitation , microstructure , oxide , inorganic chemistry , metallurgy , chemistry , organic chemistry , physics , meteorology , engineering
The catalytic performance of a Ni/MgAlO x catalyst was investigated in the high temperature CO 2 reforming of CH 4 . The catalyst was developed using a Ni, Mg, Al hydrotalcite‐like precursor obtained by co‐precipitation. Despite the high Ni loading of 55 wt%, the synthesized Ni/MgAlO x catalyst possessed a thermally stable microstructure up to 900 °C with Ni nanoparticles of 9 nm. This stability is attributed to the embedding nature of the oxide matrix, and allows increasing the reaction temperature without losing active Ni surface area. To evaluate the effect of the reaction temperature on the reforming performance and the coking behavior, two different reaction temperatures (800 and 900 °C) were investigated. At both temperatures the prepared catalyst showed high rates of CH 4 consumption. The higher temperature promotes the stability of the catalyst performance due to mitigation of the carbon formation.