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Optically Active Allenes from an Allylic Substitution/Isomerization Sequence
Author(s) -
Zhang Wenhan,
Ready Joseph M.
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300663
Subject(s) - isomerization , enantioselective synthesis , allylic rearrangement , substitution (logic) , chemistry , sequence (biology) , catalysis , tsuji–trost reaction , optically active , combinatorial chemistry , stereochemistry , organic chemistry , computer science , biochemistry , programming language
It takes two to trisubstitute: A two‐step procedure involving enantioselective allylic alkylation followed by 1,3 hydrogen shift enables the catalytic asymmetric synthesis of trisubstituted allenes.