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Deoxydehydration of Glycols Catalyzed by Carbon‐Supported Perrhenate
Author(s) -
Denning Alana L.,
Dang Huong,
Liu Zhimin,
Nicholas Kenneth M.,
Jentoft Friederike C.
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300545
Subject(s) - perrhenate , chemistry , catalysis , diol , stereoselectivity , styrene , tartrate , organic chemistry , alkene , heterogeneous catalysis , copolymer , rhenium , polymer
Support group: The first heterogeneous catalyst for the deoxydehydration (DODH) of glycols into olefins is reported. A carbon‐supported perrhenate material was found to catalyze the reductive conversions of styrene diol, tetradecane diol, and diethyl tartrate into their respective olefins with high chemo‐, regio‐, and stereoselectivity. Effective reductants for this DODH reaction include H 2 , alcohols, and tetralin.