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A Widely Applicable Regioselective Aerobic α‐Cyanation of Tertiary Amines Heterogeneously Catalyzed by Manganese Oxides
Author(s) -
Yamaguchi Kazuya,
Wang Ye,
Mizuno Noritaka
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300477
Subject(s) - cyanation , regioselectivity , catalysis , manganese , chemistry , molecular sieve , cyanide , trimethylsilyl cyanide , molecular oxygen , organometallic chemistry , octahedron , deoxygenation , combinatorial chemistry , organic chemistry , crystal structure
A fit catalyst for some aerobic exercise: A manganese oxide‐based octahedral molecular sieve, OMS‐2, could act as an efficient heterogeneous catalyst for the regioselective α‐cyanation of various tertiary amines, including trialkyl, benzylic, and N , N ‐dialkylaniline derivatives using trimethylsilyl cyanide (TMSCN) as the cyano source and molecular oxygen as the terminal oxidant.