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Air‐Promoted Adsorptive Desulfurization over Ti 0.9 Ce 0.1 O 2 Mixed Oxides from Diesel Fuel under Ambient Conditions
Author(s) -
Xiao Jing,
Sitamraju Siddarth,
Chen Yongsheng,
Janik Michael,
Song Chunshan
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300329
Subject(s) - flue gas desulfurization , adsorption , diesel fuel , oxide , chemical engineering , process (computing) , materials science , chemistry , computer science , organic chemistry , metallurgy , engineering , operating system
In the air tonight: High adsorptive desulfurization capacity of commercial diesel was achieved by using TiO 2 ‐CeO 2 mixed‐oxide adsorbents with the addition of air. Density functional theory elucidated a cyclic adsorption process, in which surface‐oxygen vacancies on the Ti 0.9 Ce 0.1 O 2 surface served as active sites.