Immobilized Ru Clusters in Nanosized Mesoporous Zirconium Silica for the Aqueous Hydrogenation of Furan Derivatives at Room Temperature | Zendy

Chen Jiazhi | Zendy; Lu Fang | Zendy; Zhang Junjie | Zendy; Yu Weiqiang | Zendy; Wang Feng | Zendy; Gao Jin | Zendy; Xu Jie | Zendy

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Immobilized Ru Clusters in Nanosized Mesoporous Zirconium Silica for the Aqueous Hydrogenation of Furan Derivatives at Room Temperature

Author(s) -

Chen Jiazhi,

Lu Fang,

Zhang Junjie,

Yu Weiqiang,

Wang Feng,

Gao Jin,

Xu Jie

Publication year - 2013

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201300316

Subject(s) - ruthenium , aqueous solution , zirconium , catalysis , mesoporous material , furan , mesoporous silica , inorganic chemistry , chemistry , hydrogen , materials science , organic chemistry

Ru lonesome tonight? Immobilized ruthenium clusters (50 Ru atoms) in nanosized mesoporous zirconium silica were synthesized by using an impregnation method starting from an aqueous solution of RuCl 3 . The Ru cluster catalysts were thermally stable at 500 °C and showed remarkable activity for the hydrogenation of furan derivatives in water at room temperature under 5 bar hydrogen pressure.

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