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Gold‐Catalyzed Intermolecular Enantioselective [2+2] Cycloadditions of Sulfonylallenamides and Styrenes
Author(s) -
Mauleón Pablo
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300282
Subject(s) - enantioselective synthesis , cyclobutene , catalysis , intermolecular force , yield (engineering) , chemistry , organic chemistry , phosphoramidite , carbon fibers , materials science , molecule , ring (chemistry) , composite number , composite material , dna , biochemistry , oligonucleotide , metallurgy
It′s hip to be square: The search for methods for the enantioselective construction of carbocycles continues to fuel new discoveries. Now, the treatment of mixtures of sulfonylallenamides and styrenes with gold(I)‐phosphoramidite complexes results in the formation of cyclobutene carbon frameworks in high yield and optical purity.