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Synthesis of Dimethyl Carbonate through Vapor‐Phase Carbonylation Catalyzed by Pd‐Doped Zeolites: Interaction of Lewis Acidic Sites and Pd Species
Author(s) -
Dong Yuanyuan,
Huang Shouying,
Wang Shengping,
Zhao Yujun,
Gong Jinlong,
Ma Xinbin
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300170
Subject(s) - catalysis , faujasite , carbonylation , chemistry , lewis acids and bases , inorganic chemistry , palladium , combinatorial chemistry , organic chemistry , carbon monoxide , zeolite
All doped up: The interaction between Lewis (L) acidic sites and Pd species in the vapor‐phase carbonylation reaction of methyl nitrite over Pd/Faujasite (FAU) catalysts is determined quantitatively. By keeping the Pd species in an electron‐deficient state, the Lewis acids of the Pd/FAU catalysts promote the synthesis of dialkyl carbonates.