Synthesis of Dimethyl Carbonate through Vapor‐Phase Carbonylation Catalyzed by Pd‐Doped Zeolites: Interaction of Lewis Acidic Sites and Pd Species | Zendy

Dong Yuanyuan | Zendy; Huang Shouying | Zendy; Wang Shengping | Zendy; Zhao Yujun | Zendy; Gong Jinlong | Zendy; Ma Xinbin | Zendy

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Synthesis of Dimethyl Carbonate through Vapor‐Phase Carbonylation Catalyzed by Pd‐Doped Zeolites: Interaction of Lewis Acidic Sites and Pd Species

Author(s) -

Dong Yuanyuan,

Huang Shouying,

Wang Shengping,

Zhao Yujun,

Gong Jinlong,

Ma Xinbin

Publication year - 2013

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201300170

Subject(s) - catalysis , faujasite , carbonylation , chemistry , lewis acids and bases , inorganic chemistry , palladium , combinatorial chemistry , organic chemistry , carbon monoxide , zeolite

All doped up: The interaction between Lewis (L) acidic sites and Pd species in the vapor‐phase carbonylation reaction of methyl nitrite over Pd/Faujasite (FAU) catalysts is determined quantitatively. By keeping the Pd species in an electron‐deficient state, the Lewis acids of the Pd/FAU catalysts promote the synthesis of dialkyl carbonates.

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