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C4‐Selective Oxidative Coupling of Thiophenes with Arylboron Compounds: Influence of Solvent Acidity and Boron Substitution
Author(s) -
Schnapperelle Ingo,
Bach Thorsten
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300167
Subject(s) - boron , oxidative coupling of methane , chemistry , oxidative phosphorylation , solvent , organic chemistry , substitution (logic) , thiophene , coupling (piping) , combinatorial chemistry , materials science , catalysis , biochemistry , computer science , metallurgy , programming language
A matter of choice: The judicious choice of acidic conditions and the arylboron compound in the oxidative coupling of thiophenes affords high chemo‐ and regioselectivities, allowing the synthesis of a broad variety of multiply substituted thiophenes.