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Direct Synthesis of Phenol from Benzene and O 2 , Regulated by NH 3 on Pt/β and Pt‐Re/ZSM‐5 Catalysts
Author(s) -
Wang Linsheng,
Yamamoto Sadaaki,
Malwadkar Sachin,
Nagamatsu Shinichi,
Sasaki Takehiko,
Hayashizaki Kenichiro,
Tada Mizuki,
Iwasawa Yasuhiro
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300166
Subject(s) - benzene , phenol , selectivity , catalysis , chemistry , computer science , combinatorial chemistry , database , organic chemistry
Best director: The direct synthesis of phenol from benzene and O 2 was performed with 78–94 % selectivity on Pt/β and Pt‐Re/ZSM‐5 catalysts, regulated by NH 3 (see figure, (1)). An alternating process (see figure, (2)‐1 and (2)‐2) afforded the selective synthesis of phenol with 83–99.8 % selectivity, whilst minimizing the consumption of NH 3 .