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Direct Synthesis of Amides from Carboxylic Acids and Amines by Using Heterogeneous Catalysts: Evidence of Surface Carboxylates as Activated Electrophilic Species
Author(s) -
Deiana Chiara,
Sakhno Yuriy,
Fabbiani Marco,
Pazzi Marco,
Vincenti Marco,
Martra Gianmario
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300164
Subject(s) - amide , electrophile , chemistry , catalysis , carboxylic acid , organic chemistry , infrared spectroscopy
Amide synthesis: In situ IR spectroscopy and HRMS provided evidence of the activation of surface carboxylates at mild temperatures (about 323 K) for the direct synthesis of amides from carboxylic acids and amines.