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Reversible Hydrogenation–Oxidative Dehydrogenation of Quinolines over a Highly Active Pt Nanowire Catalyst under Mild Conditions
Author(s) -
Ge Danhua,
Hu Lei,
Wang Jiaqing,
Li Xingming,
Qi Fenqiang,
Lu Jianmei,
Cao Xueqin,
Gu Hongwei
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300136
Subject(s) - dehydrogenation , catalysis , chemistry , nanowire , bar (unit) , combinatorial chemistry , selectivity , materials science , nanotechnology , organic chemistry , physics , meteorology
Over the wire and back again: The reversible hydrogenation–oxidative dehydrogenation of quinolines is reported by using Pt nanowire (NW) as the catalyst under mild reaction conditions. Pt NW shows high activity and selectivity in the hydrogenation of quinolines under H 2 pressure (1 bar=100 kPa), and these hydrogenation products can be easily oxidized under the same conditions in an atmosphere of oxygen (1 bar) or in air.