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Binuclear Cooperative Catalysts for the Hydrogenation and Hydroformylation of Olefins
Author(s) -
Hetterscheid Dennis G. H.,
Chikkali Samir H.,
de Bruin Bas,
Reek Joost N. H.
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201300092
Subject(s) - hydroformylation , catalysis , chemistry , residue (chemistry) , transition metal , combinatorial chemistry , enzyme catalysis , organic chemistry , rhodium
Cooperative activation of substrates simultaneously by a (transition) metal and a protein residue is a common strategy in enzyme catalysis. Cooperative dinuclear catalysis for synthetic systems is relatively underdeveloped. Here, we focus on some examples of dinuclear hydrogenation and hydroformylation reactions, with the aim to stimulate the scientific community to develop more catalytic processes based on cooperative dinuclear systems.