Cationic‐Rhodium‐Catalyzed Kinetic Resolution of Allylic Alcohols through a Redox Isomerization Reaction in a Noncoordinating Solvent | Zendy

Ren Kai | Zendy; Zhang Lei | Zendy; Hu Bei | Zendy; Zhao Mengmeng | Zendy; Tu Yahui | Zendy; Xie Xiaomin | Zendy; Zhang Tony Y. | Zendy; Zhang Zhaoguo | Zendy

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Cationic‐Rhodium‐Catalyzed Kinetic Resolution of Allylic Alcohols through a Redox Isomerization Reaction in a Noncoordinating Solvent

Author(s) -

Ren Kai,

Zhang Lei,

Hu Bei,

Zhao Mengmeng,

Tu Yahui,

Xie Xiaomin,

Zhang Tony Y.,

Zhang Zhaoguo

Publication year - 2013

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201300014

Subject(s) - allylic rearrangement , isomerization , cationic polymerization , rhodium , chemistry , catalysis , redox , solvent , kinetic resolution , photochemistry , organic chemistry , medicinal chemistry , enantioselective synthesis

On the [Rh]oad again: A series of optically pure allylic alcohols is obtained through the Rh/BINAP‐catalyzed redox isomerization of racemic allylic alcohols. An improved system involves the use of cationic rhodium and a noncoordinating solvent, in which aromatic and aliphatic allylic alcohols are effectively resolved with k f / k s ( k f =rate of fast reaction, k s =rate of slow reaction) values up to 24.

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