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Cover Picture: Thermochemistry and Reaction Barriers for the Formation of Levoglucosenone from Cellobiose (ChemCatChem 2/2012)
Author(s) -
Assary Rajeev S.,
Curtiss Larry A.
Publication year - 2012
Publication title -
chemcatchem
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201290000
Subject(s) - cellobiose , chemistry , isomerization , cellulose , pyrolysis , thermochemistry , computational chemistry , organic chemistry , catalysis , cellulase
Pyrolysis of Cellobiose The cover picture shows a likely intra‐molecular hydrogen shift during the gas phase pyrolysis of cellobiose, a subunit of cellulose. In the full paper on p. 200 ff. , R. S. Assary and L. A. Curtiss report the application of high‐level quantum chemical methods to compute the thermodynamics and reaction barriers for the formation of levoglucosenone from cellobiose, which is helpful in finding new experimental routes to this product. The computational studies predict that the ether bond cleavage in cellobiose occurs through internal hydrogen transfer in gas phase and that the activation energy required is similar to that required to activate cellulose. The initials IACT stand for the Institute for Atom‐efficient Chemical Transformations, an Energy Frontier Research Center funded by the U.S. Department of Energy.