Synthesis of Cyclic Carbonates from Epoxides and CO 2  under Mild Conditions Using a Simple, Highly Efficient Niobium‐Based Catalyst | Zendy

Monassier Antoine | Zendy; D'Elia Valerio | Zendy; Cokoja Mirza | Zendy; Dong Hailin | Zendy; Pelletier Jérémie D. A. | Zendy; Basset JeanMarie | Zendy; Kühn Fritz E. | Zendy

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Synthesis of Cyclic Carbonates from Epoxides and CO 2 under Mild Conditions Using a Simple, Highly Efficient Niobium‐Based Catalyst

Author(s) -

Monassier Antoine,

D'Elia Valerio,

Cokoja Mirza,

Dong Hailin,

Pelletier Jérémie D. A.,

Basset JeanMarie,

Kühn Fritz E.

Publication year - 2013

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201200916

Subject(s) - niobium , catalysis , transition metal , chemistry , inorganic chemistry , materials science , organic chemistry

Like a sore thumb: Niobium stands out among neighboring transition metals for its catalytic performance in the synthesis of cyclic carbonates. Readily available NbCl 5 is a very efficient catalyst for the preparation of industrially relevant carbonates at ambient temperature, low CO 2 pressure, and low concentrations. DMAP= N , N ‐dimethylaminopyridine.

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