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Model C sp 2 C sp 3 Hurtley Coupling Catalysis that Operates through a Well‐Defined Cu I /Cu III Mechanism
Author(s) -
Rovira Mireia,
Font Marc,
Ribas Xavi
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200885
Subject(s) - catalysis , product (mathematics) , coupling (piping) , mechanism (biology) , computer science , chemistry , service (business) , combinatorial chemistry , nanotechnology , physics , materials science , organic chemistry , business , mathematics , quantum mechanics , geometry , metallurgy , marketing
The Hurtley locker: The first examples of copper‐catalyzed C sp 2C sp 3cross‐coupling with the direct involvement of a Cu I /Cu III catalytic cycle are reported. The product rapidly reorganizes into a 1,2‐dihydroisoquinoline scaffold.