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Au I Catalysis on a Coordination Polymer: A Solid Porous Ligand with Free Phosphine Sites
Author(s) -
Václavík Jiří,
Servalli Marco,
Lothschütz Christian,
Szlachetko Jakub,
Ranocchiari Marco,
van Bokhoven Jeroen A.
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200844
Subject(s) - phosphine , polymer , porosity , catalysis , ligand (biochemistry) , surface modification , polymer chemistry , chemistry , coordination polymer , heterogeneous catalysis , chemical engineering , materials science , organic chemistry , biochemistry , receptor , engineering
The best things in life are free: LSK‐1 is a porous polymer with free phosphine sites homogeneously distributed within the structure. Post‐ functionalization gave a Au I ‐impregnated solid (16 % w/w) that was used as a recyclable heterogeneous catalyst.