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Ruthenium(II)Phosphite Complexes as Catalysts for the Hydrogenation of Carbon Dioxide
Author(s) -
Muller Keven,
Sun Yu,
Thiel Werner R.
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200818
Subject(s) - ruthenium , steric effects , supercritical carbon dioxide , catalysis , chemistry , carbon dioxide , organic chemistry , supercritical fluid
Ru(II) for the home team: Ruthenium complexes of simple and cheap phosphite ligands give high activities in the hydrogenation of carbon dioxide under supercritical conditions. The activities correlate well with the steric demand of the substituents.