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Supramolecular Ligands in Gold(I) Catalysis
Author(s) -
GramageDoria Rafael,
Bellini Rosalba,
Rintjema Jeroen,
Reek Joost N. H.
Publication year - 2013
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200541
Subject(s) - supramolecular chemistry , phosphoramidite , catalysis , template , combinatorial chemistry , chemistry , nanotechnology , supramolecular catalysis , ligand (biochemistry) , computer science , materials science , organic chemistry , molecule , dna , biochemistry , receptor , oligonucleotide
Golden (I): A supramolecular ligand–template strategy is applied to gold(I) catalysis. The supramolecular ligands, formed from a phosphoramidite backbone and two templates, display different regioselectivity in the hydroalkoxylation of allenes compared to non‐supramolecular analogues. Based on these findings, the catalytic activity of gold(I) complexes could be tunable at a supramolecular level.