Ruthenium‐Catalyzed Carbonylation of  ortho  CH Bonds in Arylacetamides: CH Bond Activation Utilizing a Bidentate‐Chelation System | Zendy

Shibata Kaname | Zendy; Hasegawa Nao | Zendy; Fukumoto Yoshiya | Zendy; Chatani Naoto | Zendy

Premium

Ruthenium‐Catalyzed Carbonylation of ortho CH Bonds in Arylacetamides: CH Bond Activation Utilizing a Bidentate‐Chelation System

Author(s) -

Shibata Kaname,

Hasegawa Nao,

Fukumoto Yoshiya,

Chatani Naoto

Publication year - 2012

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201200352

Subject(s) - denticity , carbonylation , chelation , chemistry , karma , moiety , catalysis , ruthenium , medicinal chemistry , combinatorial chemistry , acceptor , organic chemistry , carbon monoxide , crystal structure , philosophy , theology , buddhism , physics , condensed matter physics

Karma karma karma chelation: Direct carbonylation of CH bonds in arylacetamides was achieved using a bidentate‐chelation system. The use of 2‐pyridynylmethyl amino moiety is essential for the reaction to proceed. For achieving an efficient reaction, the presence of both ethylene (for a hydrogen acceptor) and H 2 O (probably for an efficient generation of catalytic active species) are required.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research