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Organocatalytic Stereoselective α ‐Formylation of Ketones
Author(s) -
Capdevila Montse Guiteras,
Emer Enrico,
Gualandi Andrea,
Petruzziello Diego,
Grilli Stefano,
Cozzi Pier Giorgio
Publication year - 2012
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200122
Subject(s) - formylation , enantioselective synthesis , chemistry , electrophile , organocatalysis , enamine , stereoselectivity , carbene , iodide , organic chemistry , catalysis , ketone
A formal… formyl: N ‐Methylbenzothiazolium iodide, a precursor of carbene and an electrophilic compound, has been shown to reacts with the enamine of ketones in a highly enantioselective formylation reaction.