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CH Carboxylation of Terminal Alkynes Catalyzed by Low Loadings of Silver(I)/DMSO at Ambient CO 2 Pressure
Author(s) -
Arndt Matthias,
Risto Eugen,
Krause Thilo,
Gooßen Lukas J.
Publication year - 2012
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200047
Subject(s) - carboxylation , chemistry , catalysis , carbon fixation , reagent , alkyne , reactivity (psychology) , organic chemistry , group 2 organometallic chemistry , carbon dioxide , combinatorial chemistry , molecule , medicine , alternative medicine , pathology
Terminally active: A reaction protocol that permits the CH carboxylation of alkynes at low temperatures, with mild bases, at ambient CO 2 pressure, in the presence of ppm‐quantities of an inexpensive silver catalyst.
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