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A Highly Selective Catalyst for Partial Hydrogenation of 1,3‐Butadiene: MgO‐Supported Rhodium Clusters Selectively Poisoned with CO
Author(s) -
Yardimci Dicle,
Serna Pedro,
Gates B. C.
Publication year - 2012
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201200033
Subject(s) - rhodium , 1,3 butadiene , gateway (web page) , catalysis , chemistry , combinatorial chemistry , information retrieval , organic chemistry , computer science , world wide web
A gateway to partial hydrogenation: Supported rhodium species with an essentially molecular character were precisely designed for the selective partial hydrogenation of 1,3‐butadiene to give n ‐butenes, transforming a metal that is traditionally considered unselective into one that is highly selective.
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