Iron(0) Particles: Catalytic Hydrogenations and Spectroscopic Studies | Zendy

Welther Alice | Zendy; Bauer Matthias | Zendy; Mayer Matthias | Zendy; Jacobi von Wangelin Axel | Zendy

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Iron(0) Particles: Catalytic Hydrogenations and Spectroscopic Studies

Author(s) -

Welther Alice,

Bauer Matthias,

Mayer Matthias,

Jacobi von Wangelin Axel

Publication year - 2012

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201100400

Subject(s) - catalysis , heterogeneous catalysis , domino , chemistry , oxidation state , materials science , photochemistry , chemical engineering , inorganic chemistry , organic chemistry , engineering

Ironing it out: The simple pre‐catalyst system FeCl 3 /EtMgCl was applied to the hydrogenation of various alkenes and alkynes at room temperature. Domino iron‐catalyzed allylation/hydrogenation reactions were performed under 1–4 bar H 2 . Spectroscopic studies determined the heterogeneous nature of the active catalyst species, its oxidation state (Fe 0 ), and the local structure and size of the formed particles.

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