para ‐Selective Aerobic Oxidative CH Olefination of Aminobenzenes Catalyzed by Palladium/Molybdovanadophosphoric acid/2,4,6‐Trimethylbenzoic Acid System | Zendy

Mizuta Yohei | Zendy; Obora Yasushi | Zendy; Shimizu Yosuke | Zendy; Ishii Yasutaka | Zendy

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para ‐Selective Aerobic Oxidative CH Olefination of Aminobenzenes Catalyzed by Palladium/Molybdovanadophosphoric acid/2,4,6‐Trimethylbenzoic Acid System

Author(s) -

Mizuta Yohei,

Obora Yasushi,

Shimizu Yosuke,

Ishii Yasutaka

Publication year - 2012

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201100375

Subject(s) - palladium , catalysis , stereoselectivity , chemistry , oxidative phosphorylation , organic chemistry , organic synthesis , medicinal chemistry , combinatorial chemistry , biochemistry

Pick of the bunch: Oxidative CH olefination of aminobenzenes with acrylates was achieved using a palladium/molybdovanadophosphoric acid (HPMoV)/2,4,6‐trimethylbenzoic acid (TMBA) system under O 2 (1 atm) in DMF. The highly regio‐ and stereoselective CH olefination of basic substrates such as aminobenzenes is important in organic synthesis; ( E )‐ para ‐alkenyl‐substituted aminobenzenes were produced in high yields.

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