Premium
para ‐Selective Aerobic Oxidative CH Olefination of Aminobenzenes Catalyzed by Palladium/Molybdovanadophosphoric acid/2,4,6‐Trimethylbenzoic Acid System
Author(s) -
Mizuta Yohei,
Obora Yasushi,
Shimizu Yosuke,
Ishii Yasutaka
Publication year - 2012
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201100375
Subject(s) - palladium , catalysis , stereoselectivity , chemistry , oxidative phosphorylation , organic chemistry , organic synthesis , medicinal chemistry , combinatorial chemistry , biochemistry
Pick of the bunch: Oxidative CH olefination of aminobenzenes with acrylates was achieved using a palladium/molybdovanadophosphoric acid (HPMoV)/2,4,6‐trimethylbenzoic acid (TMBA) system under O 2 (1 atm) in DMF. The highly regio‐ and stereoselective CH olefination of basic substrates such as aminobenzenes is important in organic synthesis; ( E )‐ para ‐alkenyl‐substituted aminobenzenes were produced in high yields.